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Rh<sub>2</sub>(II)-Catalyzed Selective Aminomethylene Migration from Styryl Azides

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NIAID Data Ecosystem2026-03-07 收录
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Rh2(II)-Carboxylate complexes were discovered to promote the selective migration of aminomethylenes in β,β-disubstituted styryl azides to form 2,3-disubstituted indoles. Mechanistic data are also presented that suggest that the migration occurs stepwise before diffusion of the iminium ion.

创建时间:
2016-02-19
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