Carbocyclization Cascades of Allyl Ketenimines via <i>Aza-</i>Claisen Rearrangements of <i>N-</i>Phosphoryl-<i>N-</i>allyl-ynamides
收藏NIAID Data Ecosystem2026-03-07 收录
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A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein–Wagner rearrangements and polyene-type cyclizations en route to fused bi- and tricyclic frameworks are featured.
创建时间：
2012-04-06
