Synthesis of a Stable Iminium Salt and Propellane Derivatives
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https://figshare.com/articles/dataset/Synthesis_of_a_Stable_Iminium_Salt_and_Propellane_Derivatives/2906569
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资源简介：
The treatment of morphinan 1 with NaH and MsCl provided very stable iminium salt 7 possessing propellane skeleton. One of the synthesized iminium salts 7, isobutyl derivative 7b, was crystallized and its structure was determined by X-ray crystallography. The natural bond orbital analysis suggested that the stability of the iminium should result from the stereoelectronic effect (hyperconjugation) attributed to their own structures.
创建时间：
2016-02-27
