微区选择性氧化-络合调控锑砷绿色高效分离技术数据集
收藏资源简介:
本研究探明了辉锑矿与毒砂在不同pH值和捕收剂作用下的浮选行为及作用机理,研究了矿浆pH值和氧化还原条件等对矿物颗粒表面润湿性、表面电动电位及矿物表面氧化行为的影响,解析矿物的氧化还原规律,探明了辉锑矿与毒砂在不同抑制剂体系下的浮选行为,实现毒砂的选择性抑制。使用X射线衍射、X射线光电子能谱、扫描电镜、电感耦合等离子体质谱等行业内通用的表征手段获得辉锑矿和毒砂分离的各项理化性质数据,确保了数据采集的高效性和稳定性。通过以上数据查明了辉锑矿与毒砂在不同抑制剂体系下的浮选行为,揭示了抑制剂与矿物表面选择性络合机理,开发矿物表面氧化与抑制剂络合的微区选择性调控技术,实现毒砂的选择性抑制。以上研究内容为辉锑矿与毒砂的绿色开发提供技术借鉴和参考。本数据集主要包括子任务微区选择性氧化-络合调控锑砷绿色高效分离技术中辉锑矿和毒砂的晶体化学差异以及药剂吸附差异、辉锑矿和毒砂的高效浮选分离药剂筛选、辉锑矿与毒砂在不同pH值和抑制剂作用下的浮选行为和辉锑矿、毒砂与抑制剂的作用机理等研究内容的原始及计算等数据,数据量为126.64MB。
This study clarified the flotation behaviors and interaction mechanisms of stibnite and arsenopyrite under varying pH conditions and collector treatments. It investigated the impacts of pulp pH and redox conditions on the wettability, zeta potential of mineral particle surfaces, and surface oxidation behaviors of minerals, analyzed the redox regularity of minerals, clarified the flotation behaviors of stibnite and arsenopyrite under different depressant systems, and realized the selective depression of arsenopyrite. Commonly used industrial characterization techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and inductively coupled plasma mass spectrometry (ICP-MS) were adopted to acquire various physicochemical property data for the separation of stibnite and arsenopyrite, ensuring the efficiency and stability of data acquisition. Based on the above data, the flotation behaviors of stibnite and arsenopyrite under different depressant systems were clarified, the selective complexation mechanism between depressants and mineral surfaces was revealed, and a micro-area selective regulation technology for mineral surface oxidation and depressant complexation was developed, achieving selective depression of arsenopyrite. The aforementioned research contents provide technical references for the green development and utilization of stibnite and arsenopyrite. This dataset primarily contains raw and calculated data from multiple research aspects: the crystallochemical differences and reagent adsorption differences between stibnite and arsenopyrite in the micro-area selective oxidation-complexation regulation for green and efficient separation of antimony and arsenic; the screening of efficient reagents for flotation separation of stibnite and arsenopyrite; the flotation behaviors of stibnite and arsenopyrite under different pH values and depressant actions; and the interaction mechanisms between stibnite, arsenopyrite and depressants. The total data volume is 126.64 MB.




