Synthesis and Reactivity of Sterically Encumbered Diazaferrocenes
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Sterically_Encumbered_Diazaferrocenes/2026323
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资源简介：
Bulky
pyrrolyl ligands have been used for the synthesis of diazaferrocenes,
which have been characterized by various spectroscopic techniques,
including X-ray diffraction for rac-[{η5-2,3,5-(Me3C)3C4HN}2Fe]. Chemical oxidation of diazaferrocenes to the corresponding diazaferrocenium
cations has been accomplished with AgSbF6. In addition,
EPR and Mössbauer spectroscopic, electrochemical, and density
function theory (DFT) studies have provided a more detailed understanding
of the electronic structures of these complexes.
创建时间：
2015-12-16
