Solvothermal Synthesis and Characterization of Two High-Nuclearity Mixed-Valent Manganese Phosphonate Clusters
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Solvothermal_Synthesis_and_Characterization_of_Two_High_Nuclearity_Mixed_Valent_Manganese_Phosphonate_Clusters/2940952
下载链接
链接失效反馈官方服务：
资源简介：
Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn19 cluster with a cylindrical core structure. Compound 2 possess a Mn16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers.
创建时间：
2008-05-05
