Structural Characterization of the First Hydroxo-Bridged Plutonium Compound, (PuO<sub>2</sub>)<sub>2</sub>(IO<sub>3</sub>)(μ<sub>2</sub>-OH)<sub>3</sub>
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The hydrothermal reaction of a 239Pu(IV) stock solution in the presence of iodic acid and 1 M KOH produces reddish-brown single crystals of (PuO2)2(IO3)(OH)3. The structure consists of two-dimensional layers forming in the ac plane and is the first single-crystal structure of plutonium(VI) connected through hydroxide anions. The additional linkage of plutonium centers is completed through iodate ligands.
创建时间：
2005-07-25
