A Highly Selective Fluorescent Chemosensor for Al^III Ion and Fluorescent Species Formed in the Solution

A chemosensor for the Al3+ ion, 1-[(3-hydroxypyridin-2-ylamino)­methylene]­naphthalen-2­(1H)-one (H2L), based on inhibited excited-state intramolecular proton transfer was synthesized. The experimental and theoretical calculations at B3LYP+PCM/6-31G­(d) revealed that Al3+ and H2L form a 1:1 complex, [AlL­(OH)­(H2O)]2, in dimethyl sulfoxide that exhibits two remarkably enhanced fluorescent emissions at 523 and 553 nm. It is confirmed that H2L could be used to detect Al3+ ions in cells by bioimaging.