Synthesis and Catalytic Application in Hydrosilylation of the Complex mer-Hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III)
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The sulfur-coordinated acyl(hydrido)cobalt(III) complex 1 was synthesized by reaction of thiosalicylaldehyde with CoMe(PMe3)4. The crystal structure of 1 was determined by X-ray diffraction. Complex 1 is an excellent catalyst for the hydrosilylation of aldehydes and ketones under mild conditions. This might be the first example of hydrosilylation of aldehydes and ketones catalyzed by (hydrido)cobalt complexes.
创建时间：
2016-02-18
