Salen-Based [Zn<sub>2</sub>Ln<sub>3</sub>] Complexes with Fluorescence and Single-Molecule-Magnet Properties
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A family of four isostructural complexes with a V-shaped pentanuclear [Zn2Ln3] core of general formula [Zn2Ln3(m-salen)3(N3)5(OH)2] [LnIII = TbIII (1), EuIII (2), HoIII (3), DyIII (4); m-salen = N,N′-ethylenebis(3-methoxysalicylideneamine)] were isolated and structurally characterized. The fluorescence and magnetic measurements of the four compounds were investigated. Complex 1 exhibits strong fluorescence properties, while single-molecule-magnet behavior is seen in complex 4.
创建时间：
2016-02-25
