Dynamic Figure Eight Loop Structure of <i>meso</i>-Tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0)
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3,3′-Diethyl substituents of the 2,2′-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/π interactions and remarkably accelerate syn−anti conformational change of the 2,2′-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins.
创建时间:
2016-02-26



