Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C–H Activation of Aryloxyethynyl Silanes
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https://figshare.com/articles/dataset/Synthesis_of_Benzosiloles_by_Intramolecular_i_anti_i_-Hydroarylation_via_i_ortho_i_-C_H_Activation_of_Aryloxyethynyl_Silanes/5445400
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Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-catalyzed intramolecular anti-hydroarylation of aryloxyethynyl(aryl)silanes via ortho-C–H bond activation. The aryloxy group bound to the ethynyl carbon is the key factor for this transformation.
创建时间:
2017-09-26



