Ru(0)-Catalyzed Direct Coupling of Internal Alkynes with Conjugated Dienes: An Efficient Access to Conjugated Trienes
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https://figshare.com/articles/dataset/Ru_0_-Catalyzed_Direct_Coupling_of_Internal_Alkynes_with_Conjugated_Dienes_An_Efficient_Access_to_Conjugated_Trienes/4311659
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Ru(0)-catalyzed direct coupling of internal alkynes with conjugated dienes enables a direct access to conjugated trienes, where the reaction is formally regarded as a stereoselective syn alkyne insertion into the terminal C–H bond in the conjugated diene. The reaction is catalyzed by Ru(η6-naphthalene)(η4-1,5-COD) (1; 3–10 mol %) with high regio- and stereoselectivities.
创建时间：
2016-12-12
