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(Thio)urea-Based Covalent Organic Framework as a Hydrogen-Bond-Donating Catalyst

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Figshare2020-07-01 更新2026-04-28 收录
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https://figshare.com/articles/dataset/_Thio_urea-Based_Covalent_Organic_Framework_as_a_Hydrogen-Bond-Donating_Catalyst/12546713
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Two-dimensional urea- and thiourea-containing covalent organic frameworks (COFs) were synthesized at ambient conditions at large scale within 1 h in the absence of an acid catalyst. The site-isolated urea and thiourea in the COF showed enhanced catalytic efficiency as a hydrogen-bond-donating organocatalyst compared to the molecular counterparts in epoxide ring-opening reaction, aldehyde acetalization, and Friedel–Crafts reaction. The COF catalysts also had excellent recyclability.
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2020-07-01
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