A Cyclopropenylaluminum Derivative from Hydrolysis and Alcoholysis of an Aluminacyclobutenone
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Hydrolysis and alcoholysis of the cyclic aluminum acyl LAl[C(O)C(SiMe3)C(SiMe3)] (1; L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) resulted in the formation of the cyclopropenylaluminum derivative LAl{[C3(SiMe3)2]C(O)C(SiMe3)C(SiMe3)} (2) with the elimination of aluminum hydroxides LAlOH(OR) (R = H, Et, tBu).
创建时间:
2007-03-12



