Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation
收藏Figshare2016-02-20 更新2026-04-29 收录
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Unprecedented self-sorting of three-dimensional purely organic cages driven by dynamic covalent bonds is described. Four different cages were first synthesized by condensation of two triamines and two dialdehydes separately. When a mixture of all the components was allowed to react, only two cages were formed, which suggests a high-fidelity self-recognition. The issue of the preference of one triamine for a particular dialdehyde was further probed by transforming a non-preferred combination to either of the two preferred combinations by reacting it with the appropriate triamine or dialdehyde.
创建时间：
2016-02-20
