Synthesis of γ,δ-Unsaturated and δ,ε-Unsaturated α-Amino Acids from Fragmentation of γ- and δ-Lactones
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https://figshare.com/articles/dataset/Synthesis_of_Unsaturated_and_Unsaturated_Amino_Acids_from_Fragmentation_of_and_Lactones/3350926
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资源简介：
A noncoded amino acid of cyclomarin A (1) was synthesized in a racemic fashion. The method
employs a six-membered ring template to control the relative stereochemistry and introduction of
the functional groups. Ultimately, Pd-catalyzed fragmentation of the lactone provided γ,δ-unsaturated and δ,ε-unsaturated α-amino acids. A Pd-catalyzed ring opening of a γ-lactone is also
reported.
创建时间：
2016-05-07
