Syntheses, Structures, and Crystal Packing of N-Confused 5,20-Diphenylporphyrin and Ag(III) Complex
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https://figshare.com/articles/dataset/Syntheses_Structures_and_Crystal_Packing_of_N-Confused_5_20-Diphenylporphyrin_and_Ag_III_Complex/3746073
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资源简介:
β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3
+ 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal
X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å
distance in the crystal.
创建时间:
2016-08-20



