Synthesis and Structure of a Two-Dimensional Cyano-Bridged Coordination Polymer [Cu(cyclam)]<sub>2</sub>[Mo(CN)<sub>8</sub>]·10.5H<sub>2</sub>O (Cyclam = 1,4,8,11-Tetraazacyclodecane)
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A one pot reaction between the [MoIV(CN)8]4- unit and the [Cu(cyclam)]2+ complex (cyclam = 1,4,8,11-tetraazacyclodecane) in aqueous solution yields the new cyano-bridged coordination polymer [Cu(cyclam)]2[Mo(CN)8]·10.5H2O. The compound presents an unusual two-dimensional framework with neutral zigzag sheet layers connected by hydrogen bonding. The thermal and magnetic behavior of this compound has been investigated.
创建时间：
2016-08-16
