Manganese-Based Layered Coordination Polymer: Synthesis, Structural Characterization, Magnetic Property, and Electrochemical Performance in Lithium-Ion Batteries
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https://figshare.com/articles/dataset/Manganese_Based_Layered_Coordination_Polymer_Synthesis_Structural_Characterization_Magnetic_Property_and_Electrochemical_Performance_in_Lithium_Ion_Batteries/2433160
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资源简介：
Manganese-based layered coordination
polymer ([Mn(tfbdc)(4,4′-bpy)(H2O)2],
Mn–LCP) with microporous structure was synthesized by reaction
of 2,3,5,6-tetrafluoroterephthalatic acid(H2tfbdc) and
4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate
tetrahydrate in water solution. Mn–LCP was characterized by
elemental analysis, IR spectra, thermogravimetric analysis, X-ray
single-crystal structure analysis, and powder X-ray diffraction. Magnetic
susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic
exchange between Mn(II) ions in Mn–LCP. As anode material,
the Mn–LCP electrode exhibits an irreversible high capacity
in the first discharge process and a reversible lithium storage capacity
of up to about 390 mA h/g from the fourth cycle. It might provide
a new method for finding new electrode materials in lithium-ion batteries
创建时间：
2016-02-19
