Electron-Precise/Deficient La<sub>5</sub><sub>-</sub><i><sub>x</sub></i>Ca<i><sub>x</sub></i>Ge<sub>4</sub> (3.4 ≤ <i>x</i> ≤ 3.8) and Ce<sub>5</sub><sub>-</sub><i><sub>x</sub></i>Ca<i><sub>x</sub></i>Ge<sub>4</sub> (3.0 ≤ <i>x</i> ≤ 3.3): Probing Low-Valence Electron Concentrations in Metal-Rich Gd<sub>5</sub>Si<sub>4</sub>-type Germanides
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数据链接：
https://figshare.com/articles/dataset/Electron_Precise_Deficient_La_sub_5_sub_sub_sub_i_sub_x_sub_i_Ca_i_sub_x_sub_i_Ge_sub_4_sub_3_4_i_x_i_3_8_and_Ce_sub_5_sub_sub_sub_i_sub_x_sub_i_Ca_i_sub_x_sub_i_Ge_sub_4_sub_3_0_i_x_i_3_3_Probing_Low_Valence_Electron_Concentrations_in_Metal_Rich_Gd_sub_5/3256825数据链接链接失效反馈
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资源简介：
We report for the first time the syntheses of electron-precise/deficient alloys, Ln5-xCaxGe4 (Ln = La, Ce; x = 3.37, 3.66, 3.82 for La; x = 3.00, 3.20, 3.26 for Ce), in the metal-rich R5Tt4 Zintl system (R = rare earth metal; Tt = Si, Ge). The new alloys extend the phase width from electron-rich to open-shell electron-deficient region in the metal-rich Zintl system and demonstrate possible occurrence of varied electron deficiencies in Zintl phases without structural changes, as a result of other existing structure-forming factors.
创建时间：
2016-05-05
