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Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Selective_Synthesis_of_Ruthenium_II_Metalla_2_Catenane_via_Solvent_and_Guest_Dependent_Self_Assembly/2176705
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资源简介:
The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru­(II) acceptor resulted in an interlocked metalla[2]­catenane, [M2L2]2, in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.
创建时间:
2016-02-13
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