High-Pressure Stabilization of Novel Metal-Noble-Gas Complexes and Elusive Metal Fluorides
收藏ESRF Portal2028-01-01 更新2026-04-23 收录
下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-2241571158
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资源简介：
We propose to explore in situ high-pressure DAC synthesis of novel metal-noble-gas complexes and unprecedented high-oxidation-state metal fluorides by a laser-heating-induced decomposition of extremely potent fluorinators XeF4, XeF6 and KrF+ salts. This research could provide first examples of: Xe coordination to Ag, Ir, Pt cations; coordination of Kr to a metal cation; first crystal structure of organometallic noble-gas complex; and novel high oxidation-state metal fluorides of Ag, Ir, and Au.
提供机构：
Jozef Stefan Institute, Extreme Conditions Chemistry Laboratory, Jamova cesta 39, 1000, Ljubljana, SI; Jozef Stefan Institute, Extreme Conditions Chemistry Laboratory, Jamova cesta 39, 1000, Ljubljana, SLOVENIA
创建时间：
2028-01-01
