1-D Infinite Array of Metalloporphyrin Cages
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/1_D_Infinite_Array_of_Metalloporphyrin_Cages/3318175
下载链接
链接失效反馈官方服务：
资源简介：
The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin
(H2DPyP) produces the first metal-organic coordination polymer
supported by a trans meso-bifunctional porphyrin ligand. Formulated
empirically as [Co3(DPyP)3]·4DMF, this compound exhibits a
ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon
cages as well as the inter-ribbon space. Evacuation of [Co3(DPyP)3]·4DMF at 130 °C generates [Co3(DPyP)3] that retains
crystallinity, as shown by its powder X-ray diffraction pattern, which
is consistent with that of [Co3(DPyP)3]·4DMF.
创建时间：
2016-05-06
