Carbon monoxide adsorption on anatase TiO2 nanoparticles
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https://figshare.com/articles/dataset/Binding_of_CO_on_TiO2_nanoparticles/3437654/4
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<br>Graphical abstract of the article:"On the Simple Complexity of Carbon Monoxide on Oxide Surfaces: Facet-Specific Donation and Backdonation Effects Revealed on TiO2 Anatase Nanoparticles"ChemPhysChem. doi:10.1002/cphc.201600284<br>IR and modeling studies on TiO<sub>2</sub> nanoparticles reveal that the stretching frequency of adsorbed CO results from a synergic donation/backdonation mechanism, by which the surface oxygen anions act as electron donors even if not directly bonded to the adsorbate.<br><br>This item also contains an additional figure of the Ti sites and a simplified representation of the Ti-CO bonding mechanism. Both images were created for a blog post. Further material can be found at the links below. The last link refers to the above-mentioned blog post explaining and commenting the findings of the article.<br><br>
提供机构：
figshare
创建时间：
2016-07-25
