Dynamic Covalent Michael Acceptors to Penetrate Cells: Thiol-Mediated Uptake with Tetrel-Centered Exchange Cascades, Assisted by Halogen-Bonding Switche

Original data 1. Synthesis and Characterization Compounds <strong>7</strong>, <strong>9</strong>, <strong>10</strong>, <strong>11</strong>, <strong>13</strong>, <strong>14</strong>, <strong>16</strong>, <strong>33</strong>, <strong>34</strong>, <strong>36</strong> Lab Book Page; ¹H and ¹³C NMR; IR; HRMS Compound <strong>10 </strong>Stability Test Lab Book Page UV-Vis Absorption Spectra of <strong>10</strong> and <strong>41</strong> in PBS UV- Vis Absorption Spectra of <strong>10</strong> in Buffer After 72 h Kinetics 10 h in PBS; and in AMPSO Buffer Compound <strong>22</strong> Lab Book Page Compounds <strong>47</strong>, <strong>48</strong>, <strong>53</strong>, <strong>55</strong>, <strong>56</strong> Lab Book Pages; ¹H and ¹³C NMR; IR 2. Automated High-Content High-Throughput Screening Lab Book Pages and Data 2.1. Inhibitor Screening with OPS Reporter 2.2. Cellular Uptake of MAC Reporters 2.3. Inhibitor Screening with MAC and CTO Reporters 3. Protein Uptake 3.1. Preparation and Cellular Uptake of Streptavidin Complexes Lab Book Page and Data