New Sb12 and Sb14 Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH3(p-MeC6H4Sb)12O28]4– and [BaH10(p-MeC6H4Sb)14O34]
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https://figshare.com/articles/dataset/New_Sb_sub_12_sub_and_Sb_sub_14_sub_Polyoxometalate_Frameworks_Derived_from_Arylstibonic_Acids_LiH_sub_3_sub_i_p_i_MeC_sub_6_sub_H_sub_4_sub_Sb_sub_12_sub_O_sub_28_sub_sup_4_sup_and_BaH_sub_10_sub_i_p_i_MeC_sub_6_sub_H_sub_4_sub_Sb_sub_14_sub_O_sub_34_sub/2568754
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The lithium salt of p-tolylstibonic acid contains the anion [LiH3(p-MeC6H4Sb)12O28]4–, in which the Li+ is fully enclosed within an {Sb12O28} cage with γ Keggin ion geometry; the idealized overall formula is Li5[LiH3(p-MeC6H4Sb)12O28]Br·18H2O. In contrast, Ba2+ induces the formation of the unprecedented {Sb14O34} bowl-shaped polyoxostibonate [BaH10(p-MeC6H4Sb)14O34]·4H2O. Compounds were characterized by single-crystal X-ray crystallography and by ESI-MS.
创建时间：
2016-02-22
