Metal-Free Indole–Phenacyl Bromide Cyclization: A Regioselective Synthesis of 3,5-Diarylcarbazoles
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https://figshare.com/articles/dataset/Metal-Free_Indole_Phenacyl_Bromide_Cyclization_A_Regioselective_Synthesis_of_3_5-Diarylcarbazoles/13042237
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资源简介：
A metal-free, simultaneous
triple C–C coupling cyclization
reaction between phenacyl bromides and indoles is discovered in a
highly regioselective fashion to furnish 3,5-diarylcarbazoles. DMAP
is utilized as the only reagent for the unusual and rapid cyclization
reaction to furnish all new carbazole compounds through installation
of a great diversity of substituents. A plausible radical mechanism
for the new reaction is predicted by conducting various control experiments,
competitive reactions, furoindole formation, and ESI-MS analyses of
the ongoing cyclization reaction.
创建时间：
2020-10-02
