A Novel Dumbbell-like Polyoxometalate Assembled of Copper(II)-Disubstituted Monovacant Keggin Polyoxoanions with a Tetranuclear Copper Cluster
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https://figshare.com/articles/dataset/A_Novel_Dumbbell_like_Polyoxometalate_Assembled_of_Copper_II_Disubstituted_Monovacant_Keggin_Polyoxoanions_with_a_Tetranuclear_Copper_Cluster/2314579
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资源简介：
A dimeric
Keggin polyoxometalate, [Cu(bpy)(μ2-OH)]4[(H2O)(bpy)2HPW11Cu2O39]2·2CH3CH2OH·10H2O (1), constructed from two dicopper(II)-substituted
monovacant Keggin polyoxoanions bridged by a Cu4 cluster,
has been hydrothermally synthesized. Magnetic analysis indicates predominantly
an antiferromagnetic interaction between copper(II) centers. Compound 1 also shows very high catalytic activity for the esterification
of phosphoric acid with equimolar lauryl alcohol to monoalkyl phosphate
ester.
创建时间：
2014-03-17
