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Persistent Ambipolar Heptacenes and Their Redox Species [Data]

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DataCite Commons2022-05-02 更新2025-04-17 收录
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https://heidata.uni-heidelberg.de/citation?persistentId=doi:10.11588/data/CVD7WF
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Research Data associated with the related publication. Sixfold TIPS-ethynylation combined with fourfold bromination of the armchair edges furnishes a long-lived, soluble heptacene; π-extension via Stille coupling accesses a persistent tetrabenzononacene. Both types of acenes were stabilized best by double TIPS-ethynylation on every other benzene ring. Tetrabromoheptacene is an ambipolar transistor material (up to 0.036 cm2/Vs n channel), which was corroborated by generation of its monoanion and monocation.
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2022-02-02
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