Entropy-Driven Ball-in-Bowl Assembly of Fullerene and Geodesic Phenylene Bowl
收藏Figshare2017-04-14 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Entropy-Driven_Ball-in-Bowl_Assembly_of_Fullerene_and_Geodesic_Phenylene_Bowl/4877558
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Complexation of C60 at a conical region of a nanometer-sized geodesic phenylene bowl has been demonstrated. Proton NMR spectroscopy showed formation of a 1:1 complex that was driven by entropy gains for the assembly. Crystallographic analyses revealed its unique ball-in-bowl structure, and the presence of smoothly curved surfaces was unveiled at their interfaces.
创建时间：
2017-04-14
