Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Intramolecular_Aminotrifluoromethoxylation_of_Alkenes/2095471
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资源简介：
The first catalytic trifluoromethoxylation
of unactivated alkenes has been developed, in which Pd(CH3CN)2Cl2 was used as catalyst, AgOCF3 as trifluoromethoxide source, and Selectfluor-BF4 as
oxidant. A variety of 3-OCF3 substituted piperidines were
selectively obtained in good yields. Direct evidence was provided
to address the facile reductive elimination of PdIV–OCF3 complex to form sp3 C–OCF3 bond.
创建时间：
2016-02-12
