Inorganic and Organozinc Fluorocarboxylates: Synthesis, Structure and Materials Chemistry
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https://figshare.com/articles/dataset/Inorganic_and_Organozinc_Fluorocarboxylates_Synthesis_Structure_and_Materials_Chemistry/2418295
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资源简介：
The organozinc fluorocarboxylates
RZnO2CRf and RZnO2CRf·TMEDA,
along with Zn(O2CRf)2·TMEDA
(R = Me, Et; Rf = C2F5, C3F7) have been synthesized. The structures of EtZnO2C2F5 (5), EtZnO2C3F7 (7), EtZnO2C2F5·TMEDA (11), Zn(O2C2F5)2·TMEDA (13), along with products from the adventitious reaction with
either O2 or H2O, Zn10Me4(OMe)4(O2CC2F5)12 (2), Zn9Et2(O2CC2F5)12(O)2 (6), Zn8Et4(OEt)4(O2CC3F7)6(O) (8), [Zn(O2CC3F7)2·TMEDA]2·H2O (15) have been determined.
Thin films of oriented ZnO have been deposited on glass substrates
by low-pressure chemical vapor deposition (LPCVD) using 3 and 10 as precursors, though no fluorine incorporation
in the films was noted. LPCVD using 13 as precursor also
yielded fluorine-free ZnO, but lacking the oriented growth observed
using 3, 10. However, 5, which
exhibits short intermolecular Zn···F contacts in the
solid state, thermally decomposes to bulk ZnF2.
创建时间：
2016-02-19
