five

An approach to (±)-Lingzhiol

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https://figshare.com/articles/dataset/An_approach_to_Lingzhiol/3153385
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资源简介:
(±)-Lingzhiol has been synthesized from commercially available 5,8-dimethoxytetralone in seven steps with an overall yield of 10.3% via an unprecedented acid-catalyzed semipinacol-type rearrangement. In addition, a novel strategy for the construction of the tetracyclic 5/5/6/6 core structure of lingzhiol has been developed via a tandem rearrangement/reduction/lactonization reaction.
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2016-04-11
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