Tris(pyrrolyl-α-methyl)amines that Sterically Protect a Trigonal Metal Site
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Tris_pyrrolyl_methyl_amines_that_Sterically_Protect_a_Trigonal_Metal_Site/2981005
下载链接
链接失效反馈官方服务：
资源简介：
Three substituted tris(pyrrolyl-α-methyl)amines (H3[Aryl3TPA]) (Aryl
= 2,4,6-C6H2Me3, 2,4,6-C6H2(i-Pr)3 (Trip), or 3,5-C6H3(CF3)2) have
been prepared. An X-ray study of [Trip3TPA]MoCl shows it to be
a distorted trigonal bipyramidal species in which the 2,4,6-triisopropylphenyl substituents surround and protect the apical
chloride. Attempts to prepare other Mo, Zr, and Hf complexes
yielded species in which one pyrrole-containing arm remained free
(Mo) or dimethylamine remained in the coordination sphere of
[Aryl3TPA]3- complexes (Zr, Hf).
创建时间：
2016-06-03
