Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N‑Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand
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https://figshare.com/articles/dataset/Copper_I_Catalyzed_Asymmetric_Pinacolboryl_Addition_of_i_N_i_Boc_imines_Using_a_Chiral_Sulfoxide_Phosphine_Ligand/2207308
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Highly efficient and enantioselective copper(I)-catalyzed pinacolboryl addition of N-Boc-imines is reported. By using a single chiral sulfoxide-(dialkyl)phosphine (SOP) ligand, both enantiomeric isomers of α-amino boronic esters were obtained through an achiral counteranion switch.
创建时间:
2016-02-15



