Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C–H Alumanylation of Alkenes
收藏NIAID Data Ecosystem2026-05-01 收录
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https://figshare.com/articles/dataset/Vanadium_Alumanyl_Complex_Synthesis_Characterization_Reactivity_and_Application_as_a_Catalyst_for_C_H_Alumanylation_of_Alkenes/25093367
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资源简介：
A complex
containing a V–Al bond is described. This species
can be prepared by either transmetalation of a previously disclosed
alumanylpotassium with Cp2VCl or photolytic oxidative alumination
of Cp2V using the corresponding dialumane. Reaction of
the resulting V–Al complex with H2 gave a Cp2V-dihydridoaluminate complex. These complexes were studied
with X-ray crystallography, vanadium K-edge XANES
spectroscopy, and DFT calculations. Finally, the reactivity of these
molecules was studied opening the way to a catalytic C–H alumanylation
of alkenes.
创建时间：
2024-01-27
