η<sup>2</sup>-Porphyrin Ru(II) π Complexes
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Highly stable η2-porphyrin Ru(II) π complexes have been synthesized. The formation of the η2 π bond has been facilitated through π−π stacking interactions between the porphyrin and the planar ligand on Ru. π coordination of ruthenium to porphyrin results in dramatic changes in the aromaticity and electronic properties. These properties are controllable via fine-tuning of the ligand on ruthenium.
创建时间:
2010-07-28



