A Highly Convergent and Biomimetic Total Synthesis of Portentol
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https://figshare.com/articles/dataset/A_Highly_Convergent_and_Biomimetic_Total_Synthesis_of_Portentol/2114173
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资源简介：
An efficient total
synthesis of the unusual polyketide portentol
is reported. Three boron aldol reactions were used to assemble the
linear carbon chain of the natural product, which contains two challenging anti−anti stereotriads. A biomimetic
double cyclization cascade, triggered by an oxidation, then afforded
portentol and its known dehydration product, anhydroportentol. The
biosynthesis of portentol and the biosynthetic relevance of our key
step are discussed.
创建时间：
2016-02-12
