Facile Isomerization of a Tungsten Silyl Complex to a Base-Stabilized Silylene Complex via 1,2-Migration of an Aryl Group
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https://figshare.com/articles/dataset/Facile_Isomerization_of_a_Tungsten_Silyl_Complex_to_a_Base_Stabilized_Silylene_Complex_via_1_2_Migration_of_an_Aryl_Group/3360406
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资源简介：
Irradiation of Cp*(CO)3WMe in the presence
of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)2W{κ2(Si,N)-Me2N(o-C6H4SiMe2)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)2W{κ2(Si,C)-SiMe2NMe2(o-C6H4)} (2) through 1,2-migration of the aryl
group.
创建时间：
2016-05-07
