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Pillared Two-Dimensional Metal–Organic Frameworks Based on a Lower-Rim Acid Appended Calix[4]arene

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Figshare2015-12-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Pillared_Two_Dimensional_Metal_Organic_Frameworks_Based_on_a_Lower_Rim_Acid_Appended_Calix_4_arene/2027382
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Solvothermal reactions of the lower-rim functionalized diacid calix[4]­arene 25,27-bis­(methoxycarboxylic, acid)-26,28-dihydroxy-4-tert-butylcalix­[4]­arene, (LH2) with Zn­(NO3)2·6H2O and the dipyridyl ligands 4,4′-bipyridyl (4,4′-bipy), 12-di­(4-pyridyl)­ethylene (DPE), or 4,4′-azopyridyl (4,4′-azopy) afforded a series of two-dimensional structures of the formulas {[Zn­(4,4′-bipy)­(L)]·21/4DEF}n, (1), {[Zn2(L)­(DPE)]·DEF}n (2), and {[Zn­(OH2)2(L)­(4,4′-azopy)]·DEF}n, (3) (DEF = diethylformamide).
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