A Series of [MnMo₉O₃₂]^6– Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks

Five new compounds based on the Waugh-type polyoxoanion [MnMo9O32]6– Na4Mn­[MnMo9O32]·11.5H2O (1), KNa3Mn­[MnMo9O32]·9H2O (2), Na2Ni2[MnMo9O32]·12H2O (3), l-Mn3[MnMo9O32]·13H2O (4a), d-Mn3[MnMo9O32]·13H2O (4b), and l-Ni3[MnMo9O32]·11.5H2O (5a) have been synthesized. In these compounds, with the changes of Na+/TM (TM = Mn2+, Ni2+) in the crystal, the homochiral interactions were extended from two adjacent [MnMo9O32]6– to one-dimensional (compounds 1 and 2), two-dimensional (compound 3), and three-dimensional (compounds 4 and 5) systems, respectively.