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Cobalt-Catalyzed Thiolative Lactonization of Alkynes with Double CO Incorporation

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cobalt_Catalyzed_Thiolative_Lactonization_of_Alkynes_with_Double_CO_Incorporation/2615458
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When the Co2(CO)8-catalyzed reaction of alkynes with thiols is conducted under the pressure of carbon monoxide, a novel thiolative lactonization with simultaneous introduction of two carbon monoxide molecules into the carbon–carbon triple bonds takes place successfully to afford α,β-unsaturated γ-thio-γ-lactones with excellent regioselectivity.
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2016-02-23
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