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Iron(0) Tricarbonyl Complexes of Microbially Derived Cyclohexadiene Ligands Containing Quaternary Stereocenters

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Iron_0_Tricarbonyl_Complexes_of_Microbially_Derived_Cyclohexadiene_Ligands_Containing_Quaternary_Stereocenters/2801512
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资源简介:
Tricarbonyliron(0) complexes of novel cyclohexadiene ligands possessing quaternary centers have been synthesized and characterized by 1H and 13C NMR and by X-ray crystallography. The ligands, which are derived via an unusual microbial oxidation of benzoic acid, have been shown to undergo oxidative modification postcomplexation. The factors that influence facial discrimination upon complexation are discussed.
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2016-02-25
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