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Checkerboard-Type Charge-Ordered State of a Pressure-Induced Superconductor, β-(<i>meso</i>-DMBEDT-TTF)<sub>2</sub>PF<sub>6</sub>

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To investigate the insulating state of the pressure-induced superconductor, β-(meso-DMBEDT-TTF)2PF6, we have carried out X-ray analysis at 11.5 K. In an asymmetric unit, there exist two crystallographically independent donor molecules, caused by charge separation. In the column structure, the arrangement of the charge-rich (r) and -poor (p) donor molecules is as rrpprrpp, which affords “checkerboard”-type charge ordering.

创建时间:
2016-05-05
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