Rh(II)/Brønsted Acid Cocatalyzed Intramolecular Trapping of Ammonium Ylides with Enones: Diastereoselective Synthesis of 2,2,3-Trisubstituted Indolines
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https://figshare.com/articles/dataset/Rh_II_Br_nsted_Acid_Cocatalyzed_Intramolecular_Trapping_of_Ammonium_Ylides_with_Enones_Diastereoselective_Synthesis_of_2_2_3_Trisubstituted_Indolines/2257375
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Highly diastereoselective intramolecular trapping of ammonium ylides with enones has been developed through a Rh(II)/Brønsted acid cocatalytic strategy. This process allows rapid and efficient construction of N-unprotected polyfunctional 2,2,3-trisubstituted indolines in moderate to good yields with excellent diastereoselectivity.
创建时间:
2016-02-16



