Enantioselective, Lewis Base-Catalyzed, Intermolecular Sulfenoamination of Alkenes
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https://figshare.com/articles/dataset/Enantioselective_Lewis_Base-Catalyzed_Intermolecular_Sulfenoamination_of_Alkenes/9699920
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资源简介：
A method
for the catalytic, enantioselective, intermolecular, 1,2-sulfenoamination
of alkenes is described. Functionalization is achieved through the
intermediacy of an enantioenriched, configurationally stable thiiranium
ion generated by Lewis base activation of a readily available sulfur
electrophile. A diverse set of anilines and benzylamines react with
different styrenes to afford products in good yield and stereoselectivity.
Downstream manipulation of the products is facilitated by deprotonation
of the amines to enable carbon–sulfur bond cleavage.
创建时间：
2019-08-21
