five

Three Different Dimerizations of 2-Bromo-3-methyl-1,4-naphthoquinones

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Three_Different_Dimerizations_of_2_Bromo_3_methyl_1_4_naphthoquinones/2521546
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Three types of dimeric naphthoquinones, which possess structurally diverse skeletons, can be prepared in one step from 2-bromo-3-methyl-1,4-naphthoquinones. 2,2′-Dimeric naphthoquinones were prepared by a one-pot Stille-type reaction via vinylstannanes. Oxepines are formed by unexpected domino reactions via 1,4-dihydroxynaphthalene species. Epoxides are formed by a Michael/Darzens reaction via the o-quinone methides.
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2012-05-18
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