Three Different Dimerizations of 2-Bromo-3-methyl-1,4-naphthoquinones
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https://figshare.com/articles/dataset/Three_Different_Dimerizations_of_2_Bromo_3_methyl_1_4_naphthoquinones/2521546
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资源简介:
Three types of dimeric naphthoquinones, which possess
structurally diverse skeletons, can be prepared in one step from 2-bromo-3-methyl-1,4-naphthoquinones.
2,2′-Dimeric naphthoquinones were prepared by a one-pot Stille-type
reaction via vinylstannanes. Oxepines are formed by unexpected domino
reactions via 1,4-dihydroxynaphthalene species. Epoxides are formed
by a Michael/Darzens reaction via the o-quinone methides.
创建时间:
2012-05-18



