A Polyoxometalate–Cyanometalate Multilayered Coordination Network
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https://figshare.com/articles/dataset/A_Polyoxometalate_Cyanometalate_Multilayered_Coordination_Network/2524948
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资源简介：
The reaction of the ε-Keggin polyoxometalate (POM)
[PMo12O36(OH)4{La(H2O)4}4]5+ with FeII(CN)64– under typical bench conditions at room temperature
and ambient pressure has afforded the novel [ε-PMo12O37(OH)3{La(H2O)5(Fe(CN)6)0.25}4] network, which exhibits a three-dimensional
multilayered structure. The compound has been fully characterized
by synchrotron-radiation X-ray crystallography, IR spectroscopy, elemental
analysis, and thermogravimetric analysis. This coordination network
constitutes the first example of a cyanometalate bonded to a POM unit.
创建时间：
2016-02-20
