The Total Synthesis and Structural Revision of Stagonolide D
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https://figshare.com/articles/dataset/The_Total_Synthesis_and_Structural_Revision_of_Stagonolide_D/2544724
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资源简介：
The total synthesis of the putative structure of stagonolide
D
has been completed. The relative and absolute configuration of stagonolide
D was established by synthesizing its optical antipode. The adopted
strategy involves the construction of the central macrolide employing
ring-closing metathesis (RCM), followed by selective protecting group
manipulations and a final concomitant −OTBS deprotection and
displacement of an −OMs placed next to it, resulting in the
formation of the epoxide ring.
创建时间：
2012-03-02
